Tag: conducting polymers

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Paper on Printed and Laser-Scribed Stretchable Conductors on Thin Elastomers for Soft and Wearable Electronics

“Printed and Laser-Scribed Stretchable Conductors on Thin Elastomers for Soft and Wearable Electronics”

Kirill Keller, David Grafinger and Francesco Greco
Publication Date: August 12, 2021
https://doi.org/10.3389/fmats.2021.688133

 

Abstract

As printed electronics is evolving toward applications in biosensing and wearables, the need for novel routes to fabricate flat, lightweight, stretchable conductors is increasing in importance but still represents a challenge, limiting the actual adoption of ultrathin wearable devices in real scenarios. A suitable strategy for creating soft yet robust and stretchable interconnections in the aforementioned technological applications is to use print-related techniques to pattern conductors on top of elastomer substrates. In this study, some thin elastomeric sheets—two forms of medical grade thermoplastic polyurethanes and a medical grade silicone—are considered as suitable substrates. Their mechanical, surface, and moisture barrier properties—relevant for their application in soft and wearable electronics—are first investigated. Various approaches are tested to pattern conductors, based on screen printing of 1) conducting polymer [poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)] or 2) stretchable Ag ink and 3) laser scribing of laser-induced graphene (LIG). The electromechanical properties of these materials are investigated by means of tensile testing and concurrent electrical measurements up to a maximum strain of 100%. Performance of the different stretchable conductors is compared and rationalized, evidencing the differences in onset and propagation of failure. LIG conductors embedded into MPU have shown the best compromise in terms of electromechanical performance for the envisioned application. LIG/MPU showed full recovery of initial resistance after multiple stretching up to 30% strain and recovery of functionality even after 100% stretch. These have been then used in a proof-of-concept application as connectors for a wearable tattoo biosensor, providing a stable and lightweight connection for external wiring.

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News Publications

Paper on Capacitive Coupling of Conducting Polymer Tattoo Electrodes with the Skin

“Capacitive Coupling of Conducting Polymer Tattoo Electrodes with the Skin”

The skin and the electrode interface. a) Schematization of the skin layers. The epidermis, with the stratum corneum as top layer and the electrodes adopted in the study: tattoo and Ag/AgCl electrodes. The dermis, with sweat glands, nerve ending and blood vessels. The subcutaneous tissue, composed by the hypodermis and the muscle layer. On the top-right, the equivalent circuit is adopted to model the skin. b) The electrode/skin interface through Ag/AgCl (top) and tattoo electrode (down). The equivalent circuits are represented together with the physical mechanism leading to the biosignal transduction.

Laura M. Ferrari, Usein Ismailov, Francesco Greco, Esma Ismailova
Publication Date: July 10, 2021
https://onlinelibrary.wiley.com/doi/10.1002/admi.202100352

 

Abstract

Tattoo electronics is one of the emerging technologies in skin compliant biosensing. The growing interest in their large application in health monitoring raises several interrogations on how these sensors interface with the skin. In this paper, the bioimpedance at the interface of the skin and ultra-conformable tattoo electrodes made of conducting polymers are focused on. The electrochemical characteristics of these electrodes differ from traditional gelled Ag/AgCl electrodes. The modeling of equivalent circuits in different skin-electrode configurations proposes the explanation of the biopotentials transduction mechanism. The strong agreement between the circuit model and experimental values reveals the capacitive coupling of conducting polymer tattoo electrodes where circuit’s values reflect the electrodes’ and skin physical characteristics. Additional studies underline an enhanced signal stability in inter/intra-subject evaluations using dry tattoos beneficial for broad long-term recordings. This study provides a comprehensive explanation of the skin/tattoo electrode interface model. The understanding of this interface is essential when designing next generation wearable biomonitoring devices using imperceptible interfaces.